文獻名：Fabrication of hydrophobic NiFe 2 O 4@ poly (DVB–LMA) sponge via a Pickering emulsion template method for oil/water separation

作者： Caimei Zhao,^a   Lei Chen,^b   Chuanming Yu, ^a   Binghua Hu,^a   Haoxuan Huang,^a   Yongjie Chen,^a   Xin Wang,^a   Yongshi Ye,^a   Xiaohui Zhuang^a  and  Yong Li^a  

^a Faculty of Chemistry and Environmental Science, Guangdong Ocean University, Zhanjiang, P. R. China
^b School of Civil Engineering, Guangdong Ocean University Cunjin College, Zhanjiang, P. R. China

摘要：Super-hydrophobic porous absorbents are convenient, low-cost, efficient and environment-friendly materials in the treatment of oil spills. In this work, a simple Pickering emulsion template method was employed to fabricate an interconnected porous poly(DVB–LMA) sponge. A new co-Pickering stabilization system of Span 80 and NiFe₂O₄ nanoparticles was used to prepare ultra-concentrated internal phase water-in-oil (W/O) emulsions. After further polymerization, the resulting sponges were generated, which exhibited excellent adsorption selectivity due to the super-hydrophobicity and super-lipophilicity. Furthermore, the characterization results indicated that the composites had superior thermal stability, low density, high porosity and a flexible three-dimensional porous structure. Besides, the addition of nickel ferrite nanoparticles provided the materials with extra magnetic operability. High oil adsorption capacity (up to 36.9–84.2 g g⁻¹), high oil retention, fast adsorption rate and superior reusability allowed the materials to be applied in the treatment of oily water.

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